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Identifying Conjugate Acid and Base Pairs

Two substances that differ from each other only by one proton (H+) are referred to as a conjugate acid-base pair.


Identify the acid, base, conjugate acid, and conjugate base in the following reactions:

1) HNO2(aq) + H2O(l) ⇌ H3O+(aq) + NO2-(aq)

acid base conj. acid conj. base

Write the Ka or Kb expression for this reaction:

Ka=[H3O+][NO2][HNO2]Ka=\frac{\left[H_3O^+\right]\left[NO_2^-\right]}{\left[HNO_2\right]}

  • If we were to increase Ka, would that lead to more/less dissociation into ions?
    More
  • Would this mean we have a stronger/weaker acid?
    Stronger

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2) NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH-(aq)

base acid conj. acid conj. base

Write the Ka or Kb expression for this reaction:


Kb=[NH4+][OH][NH3]Kb=\frac{\left[NH_4^+\right]\left[OH^-\right]}{\left[NH_3\right]}


  • If we were to increase Kb, would that lead to more/less OH- ions?
    more
  • Would we have a stronger/weaker base?
    stronger


Practice: Conjugate Acid-Base Pairs

In the reaction HSO4-(aq) + OH-(aq) ⇌ SO42-(aq) + H2O(l), the conjugate acid-base pairs are:
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Determine the conjugate acids for each of the following:
1. H2O
2. HCO3-
3. F-
4. CN-

Determine the conjugate bases for each of the following:
5. HSO4-
6. HCl
7. HOCN
8. CH3COOH

In the reaction:
HC2H3O2+H2OH3O++C2H3O2HC_2 H_3 O_2 + H_2 O ⇌H_3 O^+ + C_2 H_3 O_2^–
Choose the pair of substances that are both Brønsted-Lowry bases in the equilibrium reaction.