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Ground State Vs Excited State Electron Configurations

Generally, when we find electron(s) in a higher energy level than expected for ground state, the atom is in an excited state.




Image illustrating Ground State Vs Excited State Electron Configurations






Image illustrating Ground State Vs Excited State Electron Configurations


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Example: Excited State Electronic Configurations

Determine the electronic configuration for a chlorine atom that has one electron excited from the 3p orbital to the 4s orbital.


Image illustrating Example


ground state Cl: [Ne] 3s2 3p5

excited state Cl: [Ne]3s2 3p4 4s1

Example: Excited States

How many electrons would an excited atom of chlorine have?


Image illustrating Example


A. 6

B. 7

C. 16

D. 18

E. None of the above


Correct Answer: E


Excited state of chlorine has the same number of electrons as the neutral, ground state of chlorine. We do not lose or gain electrons, so the excited state has 17 electrons.

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Practice: Excited State in an Energy Level Diagram

Consider an atom of the alkali metal potassium.

a) In the energy diagram given, fill in the required number of electrons for a potassium atom and name the occupied orbitals.

Illustration for practice question: Practice: Energy Level Diagram


b) The valence electron of potassium can be excited to the next highest energy state in the same valence shell. Below, show how the energy level diagram for the excited atom of potassium has changed. Make sure to name all occupied orbitals.


Illustration for practice question: Practice: Energy Level Diagram


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Practice: Ground or Excited State

Identify the following atom or ion and decide whether it is in a ground or excited state:


Z = 26 electronic configuration: [Ar]4s23d3

Choose an answer

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