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Diamagnetic vs Paramagnetic


You may see these terms come up when talking about electron configurations.


Diamagnetic - all electrons are paired

Paramagnetic - all electrons are not paired



Are the following electron configurations diamagnetic or paramagnetic?


Cd

[Kr] 5s2 4d10

Image illustrating Diamagnetic Vs Paramagnetic


diamagnetic-all electrons are paired




Tc

[Kr] 5s2 4d5

Image illustrating Diamagnetic Vs Paramagnetic


paramagnetic-one or more electrons are unpaired


Image illustrating Diamagnetic Vs Paramagnetic


Consider the electron configuration for Na



Is it diamagnetic or paramagnetic? ________


Consider the electron configuration for Si



Is it diamagnetic or paramagnetic? ________


Consider the electron configuration for Be



Is it diamagnetic or paramagnetic? ________





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Example: Paramagnetic and Diamagnetic Species

Write the electronic configuration of the following species, and label them as D diamagnetic or P paramagnetic


Image illustrating Example



a) Sc2+

Sc: [Ar] 4s2 3d1

Sc2+: [Ar]3d1 P



b) Cr2+

Cr: [Ar] 4s2 3d4 but since the d subshell prefers to be half filled rather than partially filled the actual electron configuration is:

Cr: [Ar] 4s1 3d5

Cr2+: [Ar] 3d4 P



c) Mn7+

Mn: [Ar] 4s2 3d5

Mn7+: [Ar] or [Ne]3s23p6 D




Practice: Diamagnetic

Which of the following are diamagnetic? (select all that apply)


Illustration for practice question: Practice: Diamagnetic


Choose an answer

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Extra Practice