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MO Diagrams of p Heteronuclear Diatomics

  • MO diagrams can be drawn for heteronuclear diatomics, which means diatmoic molecules formed between two atoms of different elements. The MO diagrams do not change significantly - they are drawn in a similar way to the homonuclear diatomics (two atoms of the same element).
  • For heteronuclear diatomic molecules where it is not clear whether there will be s-p mixing or not (e.g. CO), a MO diagram will be provided and you only need to fill it up with electrons.

Ex) CO


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MO Diagrams of p and s Heteronuclear Diatomics

  • For MO diagrams between p and s elements, you are responsible for drawing the MO diagrams of these molecules.

Ex) HF














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MO Diagrams of p Heteronuclear Diatomics - Example Problem

Ex) Fill-out the MO diagram below for NO+. What is the bond order?



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MO Diagrams of p and s Heteronuclear Diatomics - Example Problem

Ex) Draw the MO diagram of OH-. What is the bond order?

See video for drawing of MO diagram. Bond order is 1.

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Practice Question: MO Diagrams of Heteronuclear Diatomics


Fill in the MO diagram below of CF. What is the bond order?