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Calculate the molar enthalpy of crystallization/freezing (∆Hfreezing) when 10.00kJ of energy are lost as 30.00g of water are frozen at 0oC. (Ans in kJ/mol)


What variables do we know?

q=-10kJ

m=30g

T=0oC



What variable are we being asked to solve for?

∆Hfreezing=?


What equation should we use to solve for this?

q=nΔH(freezing)q=n\Delta H_{\left(freezing\right)}


Rearrange to solve for the variable we want:

ΔH(freezing)=qn\Delta H_{(freezing)}=\frac{q}{n}

Solve for n:

Use the equation:

n=mMn=\frac{m}{M}


n=30g18.02gmoln=\frac{30g}{\frac{18.02g}{mol}}


n=1.665 moles

ΔH=−10kJ 1.665 moles\Delta H=-\frac{10kJ}{\ 1.665\ moles}


∆Hfreezing=-6.01 kJ/mol


Methane (CH4) has a normal boiling point of -161.6oC. At this temperature, the ΔHcondensation = -8.17kJ/mol. If 16.5g of liquid methane vapourizes, how much energy is absorbed?

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