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Thermodynamic Cycles

  • A thermodynamic cycle is a closed loop in a PV-diagram.
  • The system starts with some internal thermal energy U at the beginning of the cycle and returns to the same state with the same internal thermal energy (∆T=0).
  • Thus ∆U = 0 for any thermodynamic cycle.
ΔU=QW=0Q=W\Delta U=Q-W=0\to Q=W

  • The total work done during a thermodynamic cycle is the sum of the work done in each process within the cycle.
  • The total work is equivalent to the area enclosed by the cycle.
  • If the cycle is clockwise, 𝑊𝑜𝑟𝑘 𝑑𝑜𝑛𝑒 by 𝑡ℎ𝑒 𝑔𝑎𝑠 is Positive
  • If the cycle is counter-clockwise, 𝑊𝑜𝑟𝑘 𝑑𝑜𝑛𝑒 by 𝑡ℎ𝑒 𝑔𝑎𝑠 is Negative
An ideal gas has an initial pressure of 20 Pa and a volume of 1 m3 as shown below. It is expanded to a final volume of 3 m3 and a final pressure of 5 Pa. Determine the heat energy transferred to/from the gas.



Q = W + Δ U

W = P ΔV
= Area under the curve
= Areatriangle + Arearectangle
= 1/2 b h1 + b h2
= 1/2 (2)(15) + (2)(5)
= 25 J

Δ U = 3/2 n R T
= 3/2 ΔP ΔV = 3/2 Pf Vf - 3/2 Pi Vi
= 3/2(5)(3) - 3/2(20)(1)
= - 7.5 J

Q = W + Δ U
= 25 - 7.5 = 17.5 J
0.5 mole of a gas undergoes a cycle shown below. Find the heat has been added/removed from the gas during this cycle?
Extra Practice